From an eight-component self-sorting algorithm to a trisheterometallic scalene triangle.
نویسندگان
چکیده
Using motifs from 3-fold completive self-sorting in an eight-component library, we report on the design and fabrication of a fully dynamic trisheterometallic scalene triangle, a demanding supramolecular structure that complements the so far known triangular structures.
منابع مشابه
Merging strong and weak coordination motifs in the integrative self-sorting of a 5-component trapezoid and scalene triangle.
In a dynamic six-component library, the formation of the rather weak HETPYP-I complexation can be enforced by exploiting the orthogonality and high stability of its counterpart in the sorting process, a HETTAP complex. The concept was used in a follow-up integrative self-sorting, enabling the formation of two five-component supramolecular structures: a trapezoid and a scalene triangle.
متن کاملImpact of the level of complexity in self-sorting: Fabrication of a supramolecular scalene triangle
The impact of the level of complexity in self-sorting was elaborated through the fabrication of various scalene triangles. It turned out that the self-sorting system with a higher level of complexity was far superior to less complex sorting algorithms.
متن کاملSpontaneous and catalytic fusion of supramolecules.
Using principles of completive and integrative self-sorting, a clean supramolecule-to-supramolecule transformation is realised that involves fusion of a 3-component rectangle and a 2-component equilateral triangle into a 5-component scalene triangle. While the spontaneous process takes 15 h at 25 °C, the catalytic transformation is completed within 1 h.
متن کاملA seven-component metallosupramolecular quadrilateral with four different orthogonal complexation vertices.
The 4-fold completive self-sorting of a ten-component library (7 dissimilar donors and 3 different acceptors) resulted in the clean self-assembly of four dynamic orthogonal complexes although ≥143 combinations are conceivable. Due to the non-interference of the complexes, each ligand of the four combinations was embedded to one side of the quadrilateral to serve as a linkage at one metal corner...
متن کاملA fully dynamic five-component triangle via self-sorting.
Clean fabrication of a five-component supramolecular triangle was elaborated via self-sorting. The robustness of the dynamic triangle against external stimuli was challenged by varying both the metal ions and their ratios. Self-sorting of five components proved to be superior to that of four components.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 45 شماره
صفحات -
تاریخ انتشار 2010